I often get asked what resources I’d recommend for someone totally new to making websites. There are surprisingly few tutorials out there aimed at the complete beginner. There’s Jon Duckett’s excellent—and beautiful—book. There’s the Codebar curriculum (which I keep meaning to edit and update; it’s all on Github).
Now there’s a new resource by Damian Wielgosik called How to Code in HTML5 and CSS3. Personally, I would drop the “5” and the “3”, but that’s a minor quibble; this is a great book. It manages to introduce concepts in a logical, understandable way.
And it’s free.